You need AC to TIG alloy, as Sleepy says its to lift the oxides so you can create and control the weld pool.
When the Alternating current flows to the electrode it lifts the oxides and when it flows towards the work piece it creates the weld pool
Normally AC alternates 50 times a second (the electrical gurus here might know better than me), but the modern welders can vary higher and lower than this which creates different advantages when welding.
I find it hard to fathom how it can change so often every second but then I also find it hard to imagine how a four stroke valve can open and close 5000 times a minute
Zirconiated tungstens are the go for AC welding
Thoriated tungstens used to be the go for DC welding but the 2% of thorium in them has been deemed dangerous when grinding them so they are getting harder to find as Retailers/manufacturers now try to avoid them
Alternatives are now Lanthanated and Circoniated which I beleive can be used on both AC & DC
I have been using the Lanthanated for DC now for quite a few years but still use the Zirconiated for AC
Also note that you should reverse the polarity of you DC machine when you want to arc weld, this is due to the electrode flow, when TIG welding you want the workpiece to absorb the heat and save the non consumable electrode but when arc welding you want the consumable electrode to absorb the heat to melt into the workpiece.
Some modern machines can do this with a switch rather than physically swapping the leads over.